Parviz Soroushian - Lansing MI, US Anagi Balachandra - Lansing MI, US
International Classification:
C25B 9/00
US Classification:
204279000
Abstract:
Solid electrolyte and at least one of piezoelectric and thermoelectric materials are incorporated into material systems to provide them with self-healing and adaptive qualities. The piezoelectric and thermoelectric constituents convert the mechanical and thermal energy, respectively, concentrated in critical areas into electrical energy which, in turn, guides and drives electrolytic transport of mass within solid electrolyte towards and its electrodeposition at critical areas to render self-healing and adaptive effects. Material systems incorporating the solid electrolyte but not the piezoelectric and thermoelectric constituents are also amenable to healing and adaptive effects through external application of electric potential for electrolytic transport of mass towards and its electrodeposition at critical areas.
Parviz Soroushian - Okemos MI, US Anagi Manjula Balachandra - Okemos MI, US
International Classification:
H01B 1/00
US Classification:
252 622
Abstract:
Shaped articles with the inherent capability to evolve in response to at least one of external and internal stimuli are described. These articles comprise at least one solid electrolyte with at least one dissolved salt, and at least one interface which involves a solid electrolytes and a conductive solid. Electric potential gradients, generated within the solid electrolyte by at least one of external and internal stimuli, guide and drive the self-healing and adaptation phenomena. The electric potential gradient is generated by at least one of the following effects: (i) direct application of an electric potential across the solid electrolyte; (ii) introduction of interfaces of different electrode potentials between the solid electrolyte and conductive solids; (iii) introduction of an interface between the solid electrolyte and a conductive solid embodying atoms of lower ionization energy than at least one of the atoms forming the ions of the dissolved salt in solid electrolyte; (iv) application of external load and environmental effects which, either directly or when interacting with defects developed in the article during manufacturing and use, generate stress and temperature gradients which, in turn, produce or magnify the potential gradients between the interfaces with solid electrolyte. The mechanisms through which the electric potential gradient generated by different stimuli bring about changes in article performance involve migration of ions and their electrodeposition within the solid electrolyte and at interfaces.
Parviz Soroushian - Okemos MI, US Anagi Balachandra - Okemos MI, US
International Classification:
C23F 13/00
US Classification:
20419602
Abstract:
A solid electrolyte and a piezoelectric material are incorporated into composite shaped articles to provide them with self-healing and adaptive qualities. The piezoelectric constituent converts the mechanical energy concentrated in critical areas into electrical energy which, in turn, guides and drives electrolytic transport of mass within the solid electrolyte towards, and its electrodeposition at critical areas to render self-healing and adaptive effects.
Ultra High Performance Concrete Reinforced With Low-Cost Graphite Nanomaterials And Microfibers, And Method For Production Thereof
Ultra-high-performance cementitious materials are made using suitably functionalized and relatively low-cost carbon nanofibers and graphite platelets. Polyelectrolytes and surfactants are physisorbed upon these graphite nanomaterials in water, and dispersion of nanomaterials in water is achieved by stirring. Stable and well-dispersed suspensions of nanomaterials in water are realized without using energy-intensive and costly methods, and also without the use of materials which could hinder the hydration and strength development of ultra-high-performance cementitious materials. The water incorporating dispersed nanomaterials is then mixed with the cementitious matrix and, optionally, microfibers, and cured following standard concrete mixing and curing practices. The resulting cementitious materials incorporating graphite nanomaterials and optionally microfibers offer a desired balance of strength, toughness, abrasion resistance, moisture barrier attributes, durability and fire resistance.
Joining Via Slender Nanomaterials: Materials, Procedures And Applications Thereof
A method of joining two articles using slender nanomaterials is described. Randomly oriented nanomaterial mats or aligned nanomaterial arrays are introduced at the interface between the two articles followed by their energization via at least one of microwave irradiation and heating. The nanomaterial-to-nanomaterial and nanomaterial-to-surface contacts are enhanced by at least one of fusion, embedment and chemical reaction phenomena upon energization. The fusion, embedment and chemical reaction phenomena enhance at least one of the mechanical, electrical, thermal, durability and functional attributes of these contact points, which translate into improved properties of the joined article. The enhanced contact points enable effective use of the distinct qualities of nanomaterials towards development of joints which offer unique balances of strength, ductility, toughness, transport qualities, thermal stability, weathering resistance and other characteristics.
Nano-Engineered Structural Joints: Materials, Procedures And Applications Thereof
Anagi Manjula Balachandra - Okemos MI, US Parviz Soroushian - Okemos MI, US Mohammad Sayyar Bidgoli - Lansing MI, US
Assignee:
Metna Co. - Lansing MI
International Classification:
B32B 37/12 B32B 37/06 B32B 37/24
Abstract:
A method of joining two articles through a nano-enhanced joining medium is described. Nanomaterials are applied to the surfaces of sheets made of the joining medium via casting or spraying. Said sheets with nanomaterial coatings are then placed between the joining surfaces of the articles, and then application of pressure and heating is used to form a nano-engineered structural joint at the interface of said articles. The distinctly high specific surface area of nanomaterials and the energetic preference of their functionalized surfaces for bonding facilitate the joining process. Nano-engineered structural joints complement high strength levels with desired toughness and the compliance needed for accommodating deformation (e.g. thermal expansion) mismatches of joined articles without generating high stress levels near their interface. The limited quantity (per unit joint surface area) of nanomaterials utilized in nano-engineered joints benefits their economic viability.
Joining Via Nano-Scale Reinforced Bonding Media: Materials, Procedures And Applications Thereof
Anagi Manjula Balachandra - Okemos MI, US Parviz Soroushian - Okemos MI, US Mohammad Sayyar Bidgoli - East Lansing MI, US
Assignee:
METNA CO - Lansing MI
International Classification:
B32B 37/08 C23C 18/16 C01B 31/02 B32B 37/06
Abstract:
Method of joining articles using microscale brazing alloy particles reinforced with slender nanomaterials is described. Surface modified graphite nanomaterials were dispersed in a medium comprised of metal alloy particles, this dispersion was introduced at the interface between the joining articles followed by heating under ultra high vacuum. The nanomaterial-to-metal alloy surface contacts were enhanced by at least one of fusion, embedment and chemical reaction phenomena under high temperature and ultra high vacuum yielding true nanocomposite at the interface. The fusion, embedment and chemical reaction phenomena enhance at least one of the mechanical, electrical, thermal, durability and functional attributes of these contact points, which translate into improved properties of the joined article. The enhanced contact points enable effective use of the distinct qualities of nanomaterials towards development of joints which offer unique balances of strength, ductility, toughness, energy absorption, thermal stability, weathering resistance and other characteristics.
Micropatterned Structures For Forming A Seal With The Face Skin And Other Surfaces And Method Of Make
Jue Lu - Okemos MI, US Amirpasha Peyvandi - Lansing MI, US Saqib Ul Abideen - Lansing MI, US Anagi Balachandra - Lansing MI, US
Assignee:
METNA CO - Lansing MI
International Classification:
C09J 7/00
Abstract:
The present invention is directed towards an article suitable for attachment to facial skin or other surfaces, which comprises microfibrils and continuous microribbons. The article provides good sealing when used on a regular skin, and on a challenge skin surface with facial hair, sweat and acnes. The article also provides good adhesion and sealing on any other rough surfaces, and can be used repeatedly against different surfaces. These dry adhesives can be used for improving sealing of mask respirators, swimming goggles, or for other applications such as medical bandage, working gloves, and protective clothing seal.