Edward J. Sockell - Port Lavaca TX Joseph C. Sarna - Victoria TX Ali Kerr - Victoria TX Sanjay P. Godbole - Solon OH
International Classification:
C07C25300 C07C25500
US Classification:
558324
Abstract:
A process for the enhanced recovery of hydrogen cyanide (HCN) obtained from the reactor effluent of an ammoxidation reaction of propylene or isobutylene comprising passing the reactor effluent through a quench column, an absorber column, a first distillation column, a second distillation column, a cooler and a knock-out pot, wherein the improvement comprises contacting the vapor phase containing hydrogen cyanide with an aqueous stream.
Wilfrid G. Shaw - Lyndhurst OH Kenneth L. Bigler - Aurora OH Louis R. Trott - Solon OH Steve J. Miko - Hudson OH Vincent G. Reiling - Shaker Heights OH Michael J. Seely - Twinsburg OH Dev D. Suresh - Hudson OH Maria S. Friedrich - Lyndhurst OH Paul E. Bott - Victoria TX Edward J. Sockell - Port Lavaca TX Albert R. Shuki - Sagamore Hills OH Kenneth P. Keckler - Lima OH Frank J. Kojancic - Independence OH
Assignee:
The Standard Oil Company - Cleveland OH
International Classification:
C01C 300
US Classification:
423237
Abstract:
A process for the substantial or complete elimination of ammonium sulfate generated during the production of acrylonitrile by the direct ammoxidation of propylene/propane, ammonia and an oxygen containing gas (e. g. air) over a fluid bed catalyst wherein the improvement comprises introducing an organic compound(s) into said reactor at a location where the compound(s) reacts with substantially all of the excess ammonia without affecting the acrylonitrile yield. Preferably, the organic compound is methanol which is introduced into the reactor at below its coking temperature.
Aog Incinerator No.sub.x Emission Control Via Nh.sub.3 Injection
A process and apparatus for the reduction of NO in combustion effluent comprising injecting NH. sub. 3 into contact with the combustion effluents wherein the improvement comprising injecting the NH. sub. 3 into the combustion effluent through a venturi used to connect the incinerator means which produces the combustion effluent to the cooling means which cools the combustion effluent prior to emission into the atmosphere.
Process For Elimination Of Waste Material During Manufacture Of Acrylonitrile
Wilfrid G. Shaw - Lyndhurst OH Kenneth L. Bigler - Aurora OH Louis R. Trott - Solon OH Steve J. Miko - Hudson OH Vincent G. Reiling - Shaker Heights OH Michael J. Seely - Twinsburg OH Dev D. Suresh - Hudson OH Maria S. Friedrich - Lyndhurst OH Paul E. Bott - Victoria TX Edward J. Sockell - Port Lavaca TX Albert R. Shuki - Sagamore Hills OH Kenneth P. Keckler - Lima OH Frank J. Kocjancic - Independence OH Steven J. Rowe - Medina OH
Assignee:
The Standard Oil Company - Cleveland OH
International Classification:
C07C25332 C07C25334
US Classification:
558319
Abstract:
A process for the substantial or complete elimination of ammonium sulfate generated during the production of acrylonitrile by the direct ammoxidation of propylene/propane, ammonia and an oxygen containing gas (e. g. air) over a fluid bed catalyst wherein the improvement comprises introducing methanol into said reactor in the upper portion of the reactor at a location where the methanol reacts with at least a portion if not substantially all of the excess ammonia without affecting the acrylonitrile yield. Preferably, methanol is introduced into the reactor at below its coking temperature. In particular, when an oxygen lean fluid bed catalyst is utilized, an additional oxygen containing gas is introduced into the reaction at a distance between about 8 to 14 inches from the methanol feed location.
Hsin-Chih Wu - Parma OH Edward J. Sockell - Port Lavaca TX
Assignee:
The Standard Oil Co. - Cleveland OH
International Classification:
B01D 4700
US Classification:
55 85
Abstract:
The heavy organic material contained in the liquid bottoms from the quench column of an acrylonitrile recovery and purification system is extracted therefrom using acetonitrile as the extractant.
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