George F. Vandegrift - Bolingbrook IL Martin J. Steindler - Park Forest IL
Assignee:
The United States of America as represented by the United States Department of Energy - Washington DC
International Classification:
B01D 1300 B01D 1104
US Classification:
210638
Abstract:
A method of removing organic phosphorus-based poisonous substances from water contaminated therewith and of subsequently destroying the toxicity of the substance is disclosed. Initially, a water-immiscible organic is immobilized on a supported liquid membrane. Thereafter, the contaminated water is contacted with one side of the supported liquid membrane to selectively dissolve the phosphorus-based substance in the organic extractant. At the same time, the other side of the supported liquid membrane is contacted with a hydroxy-affording strong base to react the phosphorus-based substance dissolved by the organic extractant with a hydroxy ion. This forms a non-toxic reaction product in the base. The organic extractant can be a water-insoluble trialkyl amine, such as trilauryl amine. The phosphorus-based substance can be phosphoryl or a thiophosphoryl.
Target And Method For The Production Of Fission Product Molybdenum-99
George F. Vandegrift - Bolingbrook IL Donald R. Vissers - Naperville IL Simon L. Marshall - Woodridge IL Ravi Varma - Hinsdale IL
Assignee:
The United States of America as represented by the Department of Energy - Washington DC
International Classification:
G21G 102 C25C 334 C25D 354 C25D 546
US Classification:
376202
Abstract:
A target for the reduction of fission product Mo-99 is prepared from uranium of low U-235 enrichment by coating a structural support member with a preparatory coating of a substantially oxide-free substrate metal. Uranium metal is electrodeposited from a molten halide electrolytic bath onto a substrate metal. The electrodeposition is performed at a predetermined direct current rate or by using pulsed plating techniques which permit relaxation of accumulated uranium ion concentrations within the melt. Layers of as much as to 600 mg/cm. sup. 2 of uranium can be prepared to provide a sufficient density to produce acceptable concentrations of fission product Mo-99.
Production Of Anhydrous Aluminum Chloride Composition And Process For Electrolysis Thereof
George F. Vandegrift - Naperville IL Michael Krumpelt - Naperville IL E. Philip Horwitz - Hinsdale IL
Assignee:
The United States of America as represented by the United States Department of Energy - Washington DC
International Classification:
C25C 306 C01F 758 C01F 760
US Classification:
204 67
Abstract:
A process for producing an anhydrous aluminum chloride composition from a water-based aluminous material such as a slurry of aluminum hydroxide in a multistage extraction process in which the aluminum ion is first extracted into an organic liquid containing an acidic extractant and then extracted from the organic phase into an alkali metal chloride or chlorides to form a melt containing a mixture of chlorides of alkali metal and aluminum. In the process, the organic liquid may be recycled. In addition, the process advantageously includes an electrolysis cell for producing metallic aluminum and the alkali metal chloride or chlorides may be recycled for extraction of the aluminum from the organic phase.