James Butler - League City TX, US Olga Khabashesku - Houston TX, US James T. Merrill - Morgan TX, US
Assignee:
Fina Technology, Inc. - Houston TX
International Classification:
C07C 5/333
US Classification:
585629, 585601, 585616, 585627, 585654, 585661
Abstract:
A method for the dehydrogenation of hydrocarbons to alkenes, such as n-pentene to piperylene and n-butane to butadiene at pressures less than atmospheric utilizing a dehydrogenation catalyst are disclosed. Embodiments involve operating the dehydrogenation reactor at a pressure of 1,000 mbar or less.
James Butler - League City TX, US Olga Khabashesku - Houston TX, US Darek Wachowicz - Friendswood TX, US Callum Bailey - Humble TX, US
Assignee:
Fina Technology, Inc. - Houston TX
International Classification:
B01J 29/06 B01J 27/182
US Classification:
502 78, 502 60, 502 73, 502209, 502214
Abstract:
A group V metal/rhenium-modified molecular sieve catalyst can be used in hydrocarbon conversion reactions. Embodiments can provide a toluene conversion of at least 30 wt % with selectivity to benzene above 40 wt % and to xylenes above 40 wt % and non-aromatics selectivity of less than 2. 0 wt %.
Ionomer Compositions And Methods Of Making And Using Same
A method comprising contacting at least one metal salt of an organic acid with at least one aromatic compound in a reaction zone under conditions suitable for the formation of a polymer, wherein the metal salt of an organic acid comprises a metal and at least one unsaturated organic acid moiety. A composition comprising polystyrene and a metal salt of cinnamic acid. An article made from a composition comprising polystyrene and a metal salt of cinnamic acid. A composition comprising polystyrene and a salt of a fatty acid. An article made from a composition comprising polystyrene and a salt of a fatty acid.
Singlet Oxygen Oxidized Materials And Methods Of Making And Using Same
Olga Khabashesku - Houston TX, US Billy Ellis - Spring TX, US
International Classification:
B01J 19/12 C08F 112/08
US Classification:
5263471, 20415715
Abstract:
A method comprising irradiating a donor molecule with light to form an activated donor molecule, contacting the activated donor molecule with an acceptor molecule to form an activated acceptor molecule, and contacting the activated acceptor molecule with a substrate to generate an oxidized substrate, wherein the donor molecule is in the solid phase and the activated acceptor molecule is in the gas phase.
High Impact Polymeric Compositions And Methods Of Making And Using Same
A method comprising contacting at least one conventional elastomer, at least one singlet oxygen functionalized elastomer (SOFE), and a styrene monomer in a reaction zone under conditions suitable for the formation of a styrenic polymer composition. A method comprising contacting a reaction mixture comprising styrene, polybutadiene, and a photoperoxidized polybutadiene in a reaction zone under conditions suitable for the formation of a polymeric composition, wherein the elastomer particle size distribution in the polymeric composition does not linearly correlate with the elastomer particle size distribution in the reaction mixture. A reactor blended polymer comprising styrene, a conventional elastomer, and a singlet oxygen functionalized elastomer.
Olga Khabashesku - Houston TX, US Billy Ellis - Georgetown TX, US
Assignee:
Fina Technology, Inc. - Houston TX
International Classification:
G01F 1/00 C09K 3/00 C08F 112/08
US Classification:
73861, 25218311, 5263292
Abstract:
A method for the in-situ preparation of an ionic comonomer, such as zinc dimethacrylate, dissolved in styrene monomer, for use in production of polystyrene is disclosed. The method generally includes adding comonomer chemical precursors to a solution of styrene and nonionic surfactant. The resulting ionic comonomer may be further dissolved in styrene and polymerized to form a product that may have improved properties.
Polymeric Compositions And Polymerization Initiators Using Photo-Peroxidation Process
A rubber-modified polymeric composition having predominately core-shell morphology is disclosed. The rubber-modified polymeric composition can be a polystyrene comprising styrene, polybutadiene, and a high-grafting initiator formed by contacting singlet oxygen with an olefin containing an allylic hydrogen or a diene to form a hydroperoxide or peroxide. The singlet oxygen can be formed by contacting ground state oxygen with a photo catalyst, such a photosensitive dye exposed to light.
Olga Khabashesku - Houston TX, US Scott Cooper - Humble TX, US
Assignee:
Fina Technology, Inc. - Houston TX
International Classification:
C08L 67/06
US Classification:
525451
Abstract:
A method for the in-situ preparation of an ionic comonomer from its chemical precursors, prepared in a solution of styrene monomer is disclosed. In one embodiment, the ionic comonomer is zirconium methacrylate, Zr(MA)or zirconyl methacrylate, ZrO(MA), or a combination thereof, and zirconium carbonate hydroxide oxide, ZrCO(OH).ZrO2, and methacrylic acid, CH═C(CH)—COOH, are used as precursors used for its in-situ preparation.
Resumes
Director, Research And Development At Advanced Aromatics, The Heritage Group
Director, Research and Development at Advanced Aromatics
Location:
Houston, Texas Area
Industry:
Oil & Energy
Work:
Advanced Aromatics since May 2011
Director, Research and Development
Total Petrochemicals 2008 - 2011
Manager, Base Chemicals and Technolgy Advisor
Total Petrochemicals 2006 - 2008
Sr. Research Chemist, Polystyrene Research
SABIC 2001 - 2006
Research Associate
ExxonMobil 1999 - 2000
Research Chemist
Education:
University of Houston, C.T. Bauer College of Business 2002 - 2005
MBA
Rice University 1995 - 1997
Postdoctoral Fellow, Chemistry, Spectroscopy, Biochemistry, Pharmaceuticals