Igor Chorvath - Midland MI Frances Marie Fournier - Flint MI Christopher James Julien - Freeland MI Michael Kang-Jen Lee - Midland MI Dawei Li - Midland MI Jun Liao - Midland MI Robert Leo Oldinski - Bay City MI Richard Leroy Rabe - Midland MI David Joseph Romenesko - Midland MI Thomas John Tangney - Midland MI Yongjun Lee - Hiratsuka, JP Koji Nakanishi - Ichihara, JP
Thermoplastic elastomers are disclosed which are prepared by; (I) mixing, (A) a thermoplastic resin comprising more than 50 percent by volume of a polyamide or a polyester resin, (B) a silicone base comprising; (Bâ) 100 parts by weight of a diorganopolysiloxane gum having a plasticity of at least 30 and having an average of at least 2 alkenyl groups per molecule and (Bâ) 5 to 200 parts by weight of a reinforcing filler, wherein the weight ratio of said silicone base to said polyamide or polyester resin is from 35:65 to 85:15, (C) a compatibilizer, (D) a radical initiator, present in an amount sufficient to cure said diorganopolysiloxane gum, and optionally (E) a stabilizer, (II) dynamically vulcanizing said diorganopolysiloxanes gum, wherein at least one property of the thermoplastic elastomer selected from tensile strength or elongation is at least 25% greater than the respective property for a corresponding simple blend wherein said diorganopolysiloxane is not cured and said thermoplastic elastomer has an elongation of at least 25%.
Igor Chorvath - Midland MI Dean Curtis Gray - Midland MI Michal Kang-Jen Lee - Midland MI Thomas John Tangney - Midland MI
Assignee:
Dow Corning Corporation - Midland MI
International Classification:
C08L 8307
US Classification:
524588, 524866, 524860, 524291, 524343, 524342
Abstract:
Polyolefin thermoplastic elastomers are disclosed which are prepared by; (I) mixing (A) a thermoplastic resin comprising more than 50 percent by volume of a polyolefin resin, said thermoplastic resin having a softening point of 23Â C. to 300Â C. ; (B) a silicone base comprising (Bâ) 100 parts by weight of a diorganopolysiloxane gum having a plasticity of at least 30 and having an average of at least 2 alkenyl groups per molecule, and optionally, (Bâ) up to 200 parts by weight of a reinforcing filler, the weight ratio of said silicone base to said polyolefin thermoplastic resin is from 35:65 to 85:15; (C) a radical initiator, present in an amount sufficient to cure said diorganopolysiloxane gum (Bâ); and (II) dynamically vulcanizing said diorganopolysiloxane gum, wherein at least one property of the thermoplastic elastomer selected from tensile strength or elongation is at least 25% greater than the respective property for a corresponding simple blend wherein said diorganopolysiloxane gum is not cured and said thermoplastic elastomer has an elongation of at least 25%.
Gerald Alphonse Gornowicz - Longboat Key FL Craig Steven Gross - Midland MI Mark Daniel Hartmann - Midland MI Jun Liao - Midland MI Jeffrey Paul Sage - Midland MI Gifford Neale Shearer - Midland MI Thomas John Tangney - Copley OH
Assignee:
Dow Corning Corporation - Midland MI
International Classification:
C08L 8306
US Classification:
525478, 524588
Abstract:
Re-processable thermoplastic elastomer composition comprising (A) a thermoplastic polyurethane polymer, and (B) a silicone elastomer, wherein the weight ratio of the silicone elastomer to the thermoplastic polyurethane polymer is from 5:95 to 85:15, are disclosed along with methods for making such compositions.
Silicones Bearing Acylated Diaminohydrocarbyl Radicals And Method Therefor
Thomas J. Tangney - Midland MI Maris J. Ziemelis - Midland MI
Assignee:
Dow Corning Corporation - Midland MI
International Classification:
C08G 7704
US Classification:
528 26
Abstract:
Aminofunctional siloxanes, such as siloxanes bearing ethylenediamine-substituted hydrocarbon radicals, have their amine functionality fully modified by reaction with a monocarboxylic acid anhydride. The modifying functionality includes complete diamide or amide-amine salt formation. The amide-amine salt functionality can further be converted to a mixture of diamide and amide-amine functionality, if desired. The modified aminofunctional siloxanes have utility as components in hair care compositions, textile treating compositions and moldable polymeric compositions.
Fluorosilicone Compounds And Compositions For Adhesive Release Liners
Craig K. Kendziorski - Midland MI Charles E. Neal - Midland MI Loretta A. Sobieski - Midland MI Thomas J. Tangney - Midland MI David L. Stickles - Midland MI
Assignee:
Dow Corning Corporation - Midland MI
International Classification:
C08G 7706
US Classification:
528 15
Abstract:
A new organohydrogenpolysiloxane compound and a new fluorosilicone polymer each have unique properties which allow for the preparation of faster curing coating compositions having longer bath life than those disclosed in the art. In a preferred embodiment the new polymers are mixed together to provide, along with a metal-containing hydrosilylation catalyst and a catalyst inhibitor to provide improved coating compositions which are useful for preparing a release liner to protect silicone pressure sensitive adhesives.
Addition-curable silicone pressure sensitive adhesives can be covered with an addition-cured fluorosilicone release coating to provide a releasable laminate. The release force of the laminate is low to moderate and the subsequent adhesion and tack of the adhesive is high and all three values are stable with time. The laminate can be prepared by contacting the release coating with cured adhesive or by curing the adhesive in contact with the release coating.
Yuji Hamada - Chiba, JP Akihiko Shirahata - Chiba, JP Thomas J. Tangney - Midland MI
Assignee:
Dow Corning Corporation - Midland MI Dow Corning Toray Silicone Company, Ltd. - Tokyo
International Classification:
C08F28300
US Classification:
525477
Abstract:
The subsequent tack and adhesion of a silicone pressure-sensitive adhesive can be improved by incorporating into the adhesive a small amount of an organopolysiloxane resin having a majority of R. sub. 3 SiO. sub. 1/2 siloxane units and the balance (R. sup. 2 O). sub. a SiO. sub. (4-a)/2, preferably SiO. sub. 4/2, siloxane units. The resulting composition, when brought into contact with a release liner, such a peelable protective sheet or the backside of the next turn in a roll of tape, have better tack and/or adhesion when separated from that liner than an analogous composition which does not contain the resin.
Method For Producing Dual Zone Materials By Use Of An Organosilane Mixture
Dwight E. Williams - Midland MI Thomas J. Tangney - Midland MI
Assignee:
Dow Corning Corporation - Midland MI
International Classification:
B01J 2032 B01J 2022 B01D 1508 B32B 514
US Classification:
502401
Abstract:
Dual zone porous materials having an external zone and an internal zone are prepared by contacting a suspension of a porous support, such as particulate silica, in an aprotic solvent with an organosilane mixture of a first organosilane having first silyl groups and a second organosilane of a second type in order to form first silyl groups predominantly or the external surfaces of the porous support and second silyl groups predominantly on the internal surfaces of the porous support.
Dow Corning 2008 - 2011
Global Automotive Director
Education:
Saginaw Valley State University
Bachelors, Bachelor of Science, Chemistry
Skills:
Chemistry Business Strategy Marketing Leadership Polymers Chemical Engineering Coatings Market Development Adhesives Plastics Additives Cross Functional Team Leadership
Thomas Tangney 1982 graduate of Rocky Hill High School in Rocky hill, CT is on Memory Lane. Get caught up with Thomas and other high school alumni from