Hans-Ulrich Wustefeld - Bottrop, DE William Kaska - Goleta CA, US Galen Stucky - Goleta CA, US Ferdi Schuth - Mullheim an der Ruhr, DE Bernt Krebs - Munster, DE
Assignee:
Studiengesellschaft Kohle MbH - Mulheim an der Ruhr
International Classification:
C07F 15/00
US Classification:
556136000, 546002000
Abstract:
Transition metal complexes with quino[7,8-h]quinolines and cyclopentadieno[1,2-h:4,3-h′]diquinolines as proton sponge ligands and a process for their preparation. These complexes are suitable as catalysts, e.g. the palladium complexes for a Heck reaction, as well as for amination and C—H activation reactions. The platinum and palladium complexes are potentially good cytostatic agents.
William C. Kaska - Goleta CA Craig M. Jensen - Kailua HI
Assignee:
The Regents of the University of California - Oakland CA University of Hawaii - Honolulu HI
International Classification:
C07C 5327 C07C 5373 C07C 5333 C07F 1502
US Classification:
585654
Abstract:
An improved process is described for the catalytic dehydrogenation of organic molecules having a ##STR1## group to produce a ##STR2## group. The organic molecules are: ##STR3## wherein: A. sup. 1, A. sup. 2, A. sup. 3, and A. sup. 4 are each independently P, As or N: E. sup. 2 is independently C or N; E. sup. 3 is independently C, Si or Ge; E. sup. 4 is independently C, Si, or Ge; and E. sup. 5 is independently C, Si or Ge; M. sup. 1, M. sup. 2, M. sup. 3, and M. sup. 4 each is a metal atom independently selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium and platinum; Q. sup. 1, Q. sup. 2, Q. sup. 3, and Q. sup. 4 are each independently a direct bond, --CH. sub. 2 --, --CH. sub. 2 CH. sub. 2 --, or CH. dbd.